Controlling the electronic state of two-layer molybdenum disulfide in an origami manner

(Controlling the electronic state of two-layer molybdenum disulfide in an origami manner )

In recent years, transition metal dichalcogenide was one of the key two-dimensional materials for quantum functional applications. These materials have a honeycomb like graphene but have spin-orbit coupling that allows them to exhibit novel properties. As an example, molybdenum isosulfide’s energy band structure evolved from a multilayer to monoatomic layer from an indirect band to a directly band, resulting in a significant improvement of the light absorption and fluorescence. Molybdenum sulfur has a newly discovered electronic state: the energy quantum, which can also be regarded the third internal degree freedom of electrons following charge and spin. It is important to understand the mechanisms behind these quantum phenomena in order to manipulate them. This will be of great benefit to condensed matter science and future electronics and optoelectronics.

According to Professor Wu Shiwei’s idea, this work is based upon the “ultra thin” nature of the two-dimensional quantum functional material: the monoatomic layers are folded directly, like a paper, resulting in a double, which cannot be produced by natural crystallization, or epitaxial development. Layer structure. Molybdenum Disulfide “origami” has many interlayer arrangements depending on the direction of fold and the position the fold line. This in turn results in different macrostructures symmetry and interlayer couple. The research team combined first-principles computations with various experimental techniques including fluorescence spectroscopy and optical depolarization to study the spatial electronic structure of various types molybdenum “origami”.

In addition, the change of interlayer coupling not only can greatly affect indirect band gaps in molybdenum-disulfide “origami”, but it can also be used to switch the relationship between spine and electron spin when “folding the paper”. Changes in the interlayer coupling have a significant impact on the indirect band gap in molybdenum-disulfide “origami”, and can be used in the “folding paper” relationship between spine and electrons. This work provides an experimental platform that allows for the manipulation of interactions between multiple degrees of free will, including valley, spin and interlayer coupling.

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(Controlling the electronic state of two-layer molybdenum disulfide in an origami manner )